Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering
College
College of Science
Department/Unit
Chemistry
Document Type
Article
Source Title
Manila Journal of Science
Volume
6
Issue
1
First Page
33
Last Page
37
Publication Date
2010
Abstract
Naphthalocyanines (Nc) are ideal molecular conductors due to their flat and fully-conjugated structures. Attachment of a central metal (Co) and dicyano (CN) axial ligands to Nc produced CN-bridged cobalt naphthalocynanine, a skewed-type polymer complex. The polymeric species enabled intra-chain electron transport through the CN bridge by which, coupled with the inter-chain π-π overlaps, produced a multi-dimensional electronic system. This molecular design has decreased the electrical resistivity by 5 orders relative to the monomeric Co(Nc) with di-axial CN complex.
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Recommended Citation
Yu, D. C., Gacho, E. H., Janairo, G. C., Ang, P., & Tan, S. (2010). Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering. Manila Journal of Science, 6 (1), 33-37. Retrieved from https://animorepository.dlsu.edu.ph/faculty_research/7323
Disciplines
Chemical Engineering
Keywords
Electric conductors; Heterocyclic compounds
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