"Chemical constituents of Dracontomelon Dao (Blanco) Merr. et Rolfe" by Consolacion Y. Ragasa, Tyson C. Batarra et al.
 

Chemical constituents of Dracontomelon Dao (Blanco) Merr. et Rolfe

College

College of Science

Department/Unit

Chemistry

Document Type

Article

Source Title

Pharmacognosy Journal

Volume

9

Issue

5

First Page

654

Last Page

656

Publication Date

9-1-2017

Abstract

Introduction: The leaves, twigs and flowers of Dracontomelon dao (Blanco) Merr. et Rolfe, an indigenous Philippine tree were investigated for their chemical constituents. Methods: The compounds were isolated by silica gel chromatography and their structures were identified by NMR spectroscopy. Results: Chemical investigation of D. dao led to the isolation of cardol (1), β-sitosteryl-3β-glucopyranoside-6, O-fatty acid esters (2), β-sitosteryl fatty acid esters (3), and a mixture of β-sitosterol (4a) and stigmasterol (4b) from the petiole; 1, a mixture of 4a and 4b, anacardic acid (5), triacylglycerols (6), monoacylglycerol (7), long-chain fatty acid esters (8), and linoleic acid (9) from the twigs; and a mixture of 4a and 4b, 5, 6, 8, long-chain fatty alcohols (10), and long- chain hydrocatbons (11) from the flowers of D. dao.The structures of 1 and 5 were elucidated by extensive 1D and 2D NMR spectroscopy, while those of 2-4 and 6-11 were identified by NMR spectroscopy. Conclusion: This is the first report on the isolation of 1, 4b and 6-9 from D. dao. Key words: Dracontomelon Dao (Blanco) Merr. et Rolfe, Anacardaceae, Cardol, Anacardic Acid, 3-Alkylphenols, B-Sitosteryl-3β-Glucopyranoside-6'-O-Fatty Acid Esters, B-Sitosteryl Fatty Acid Esters. © 2017 Phcog.Net.

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Digitial Object Identifier (DOI)

10.5530/pj.2017.5.103

Disciplines

Chemistry

Keywords

Spondias—Composition; Spondias—Philippines

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