Date of Publication
4-1993
Document Type
Master's Thesis
Degree Name
Master of Science in Chemistry
Subject Categories
Chemistry | Physical Chemistry
College
College of Science
Department/Unit
Chemistry
Thesis Adviser
Wyona C. Patalinghug
Defense Panel Chair
Martin C. Ilao
Defense Panel Member
Gerardo C. Janairo
Consolacion Y. Ragasa
Abstract/Summary
The crystal structure of the vanadium(III) complex, Na[V(npdta)], was determined by single crystal x-ray diffraction techniques. The complex, NapV(npdta)] belongs to the monoclinic crystal system of the space group A a (No. 9), where a = 12.026(1) A b = 12.748(1) A c = 10.580(1) A B = 93.91 degrees V = 1618.1(2) A3 Z = 4 calculated d = 1.66 g/cm3 and Rw = 0.039. The crystal structure analysis revealed that the hexadentate ligand coordinates to vanadium(III) in a distorted octahedral manner. The acqueous solution of the complex was found to exhibit thermochromism with an isosbestic point at 700 nm.
Abstract Format
html
Language
English
Format
Electronic
Accession Number
TG02815
Shelf Location
Archives, The Learning Commons, 12F Henry Sy Sr. Hall
Physical Description
47 leaves
Keywords
Ligands; Coordination compounds; Crystal field theory; Chemistry, Physical and theoretical; Vanadium
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Recommended Citation
Robles, J. C. (1993). Crystal structure study of a vanadium (III) complex containing a neopentanediamminetetraacetate ligand. Retrieved from https://animorepository.dlsu.edu.ph/etd_masteral/1942
