Nanoscale coatings of AuAlx and PtAlx and their mesoporous elemental derivatives

College

College of Science

Department/Unit

Physics

Document Type

Article

Source Title

Current Applied Physics

Volume

6

First Page

440

Last Page

443

Publication Date

6-2006

Abstract

A method to produce nanoscale films of AuAlx and PtAlx, and their mesoporous elemental derivatives is described, and the morphology and optical properties of these coatings explored. The color of the AuAlx film is bright purple, in agreement with ab initio calculations and experimental observations for the compound AuAl2, but becomes black after de-alloying with NaOH. The film of PtAlx is silver-grey and changes to grey after being converted to mesoporous Pt by de-alloying. Both mesoporous coatings exhibit a very rough surface, with pores of between 2 and 20 nm in diameter, and display a significantly more absorptive optical characteristic compared to their ordinary elemental counterparts.

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Disciplines

Physics

Keywords

Gold—Optical properties; Platinum—Optical properties; Mesoporous materials—Optical properties

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