Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives
College
College of Science
Department/Unit
Chemistry
Document Type
Article
Source Title
Journal of the Chemical Society, Perkin Transactions
Volume
1
First Page
2715
Last Page
2720
Publication Date
1994
Abstract
The p-acetoxybenzylsulfanyl protecting group is compatible with the triethylphosphite mediated cross-coupling of 4,5-bis(alkylsulfanyl)-1,3-dithiol-2-ones, providing access to bis(protected)tetrathiafulvalenes, and thus to tetrathiafulvalenedithiolate dianion 10, which can be alkylated to give unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives.
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Recommended Citation
Gemmell, C., Janairo, G. C., Kilburn, J. D., Ueck, H., & Underhill, A. E. (1994). Synthesis of unsymmetrical tetrakis(alkylsulfanyl)tetrathiafulvalene derivatives. Journal of the Chemical Society, Perkin Transactions, 1, 2715-2720. Retrieved from https://animorepository.dlsu.edu.ph/faculty_research/6734
Disciplines
Chemistry
Keywords
Tetrathiafulvalene
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