Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]

Authors

Victor Francis C. Bathan, De La Salle University, Manila
Francisco C. Franco, De La Salle University, Manila
Lourdes P. Guidote, De La Salle University, Manila

College

College of Science

Department/Unit

Chemistry

Document Type

Conference Proceeding

Source Title

22nd Philippine Chemistry Congress

Publication Date

4-2007

Abstract

Cu₂(B(3.5- diMe)BAPS)(µ-OME)₂ (1) was reacted with (CH₃)₃SICI (2) to yield a [µ-Si(CH₃)₂] (3) dicopper complex. The reaction, separation and drying of the product was carried out under dry nitrogen condition. The reaction was monitored using TLC and the separations were done using column chromatography. The product was characterized using IR, NMR, UV-Vis and ES-MS. Analysis of the separated product firmly supports the yielding of Cu₂(B(3.5- dime)BAPS)(µ-Si(CH₃)₂)₂(H₂O)₂

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Recommended Citation

Bathan, V. C., Franco, F. C., & Guidote, L. P. (2007). Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]. 22nd Philippine Chemistry Congress Retrieved from https://animorepository.dlsu.edu.ph/faculty_research/5902

Disciplines

Chemistry

Note

Abstract only

Keywords

Copper compounds; Separation (Technology)

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