Changes in minority carrier lifetime of hydrogen-terminated Si surfaces in dry-and wet-air

College

College of Science

Department/Unit

Chemistry

Document Type

Article

Source Title

ECS Solid State Letters

Volume

1

Issue

6

First Page

P89

Last Page

P91

Publication Date

9-27-2012

Abstract

Minority carrier lifetime of HF-treated Si (100) surfaces decreases in wet-air more rapidly than in dry-air. XPS measurements show that OH and O are mainly included in Si by keeping in wet-air and dry-air, respectively. OH cannot form network, and thus backbonded OH generates Si dangling bonds. On the other hand, backbonded O can form Si-O-Si networks, leading to the higher lifetime due to lower defect density. When the atmosphere is switched from dry-air to wet-air, the lifetime greatly decreases, and the workfunction increases. These changes are attributed to dominant formation of backbonded OH.

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Disciplines

Chemistry

Keywords

Silicon—Surfaces; Silicon—Oxidation; Semiconductors

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