"Complex balanced equilibria of weakly reversible power law kinetic sys" by Dylan Antonio S.J. Talabis, Eduardo R. Mendoza et al.
 

Complex balanced equilibria of weakly reversible power law kinetic systems

College

College of Science

Department/Unit

Mathematics and Statistics Department

Document Type

Article

Source Title

Mathematics

Volume

82

Issue

3

First Page

601

Last Page

624

Publication Date

1-1-2019

Abstract

In this paper, we use the concept of kinetic reactant deficiency to determine the existence of complex balanced equilibria of power law kinetic systems. We previously introduced a class of power law kinetic systems whose kinetic order vectors (which we call “interactions”) are reactant-determined (i.e. reactions with the same reactant complex have identical vectors) and are linear independent per linkage class, denoted by PL-TIK systems. A subset of PL-TIK systems was found to admit a complex balanced equilibrium. In this work, we prove that zero kinetic reactant deficiency systems are precisely the PL-TIK systems. Our main result is the existence of complex balanced equilibria for weakly reversible systems with zero kinetic reactant deficiency (for any rate constant), hence, generalizing the previous study. © 2019 University of Kragujevac, Faculty of Science. All rights reserved.

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Disciplines

Mathematics

Keywords

Chemical kinetics; Equilibrium

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