Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex

College

College of Science

Department/Unit

Chemistry

Document Type

Article

Source Title

Organometallics

Volume

22

Issue

1

First Page

195

Last Page

198

Publication Date

1-6-2003

Abstract

The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp ring in a tosylimido-bridged cobaltadithiolene complex was investigated, and a probable intermediate was isolated and characterized. The presence of a large excess of PPh3 causes the formation of the imido- and phosphine-substituted Cp complex.

html

Digitial Object Identifier (DOI)

10.1021/om0207212

Disciplines

Chemistry

Keywords

Phosphine; Cobalt compounds; Phosphorus compounds; Transition metals

Upload File

wf_no

This document is currently not available here.

Share

COinS