Modified abaca fiber prepared by radiation-induced graft polymerization as a reinforcement for unsaturated polyester resin composites

College

College of Science

Department/Unit

Chemistry

Document Type

Article

Source Title

Polymer Journal

Volume

56

First Page

97

Last Page

105

Publication Date

2024

Abstract

In this study, the preparation and characterization of unsaturated polyester resin (UPR) composites reinforced with abaca fibers modified using radiation-induced graft polymerization are investigated. The aim is to assess the influences of these modified abaca fibers as reinforcement materials on the thermal stability, moisture resistance, and mechanical properties of the composites. The results demonstrate significant enhancements in the tensile and flexural strengths of the prepared composites relative to those reinforced with untreated fibers, yielding minimum increases of 23% in tensile strength and 59% in flexural strength. The most substantial improvement is achieved with abaca fibers modified through the reversible addition −fragmentation chain-transfer–mediated grafting mechanism. In addition, short, grafted chains on abaca fibers produce the greatest enhancement in mechanical strength. The modified composites exhibit improved thermal stability and moisture resistance. These enhancements can be attributed to the improved interfacial adhesion between the modified abaca fibers and the UPR matrix, as confirmed by scanning electron microscope analysis. Overall, these findings highlight the potential of this approach as a surface modification technique for enhancing the applicability of natural fibers in the composite industry.

html

Disciplines

Chemistry

Keywords

Fibrous composites; Abaca (Fiber); Polymerization

Upload File

wf_no

This document is currently not available here.

Share

COinS