One-step synthesis of partially oxidized cobalt(III) phthalocyanine salts with axial ligands

College

College of Science

Department/Unit

Chemistry

Document Type

Article

Source Title

Chemistry Letters

Volume

35

Issue

6

First Page

602

Last Page

603

Publication Date

2006

Abstract

The one-pot syntheses of partially oxidized cobalt(III) phthalocyanine salts with axial halides, as well as a shorter route (single-step) for the axial dicyano counterpart are reported. The method utilizes an electrolytic reaction, and appears to be solvent dependent. Overlap integral calculations and electrical transport measurements indicate axial ligand effects on the molecular stacking of the cobalt phthalocyanine.

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Disciplines

Chemistry | Materials Chemistry

Keywords

Phthalocyanines; Cobalt compounds; Ligands

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