Mesoscopic heterogeneity in re-gelation of supramolecular gel

College

College of Science

Department/Unit

Chemistry

Document Type

Archival Material/Manuscript

Publication Date

2014

Abstract

A dispersion of a peptide amphiphile into water forms hierarchical fibril structures, leading to a supramolecular hydrogel. In contrast to polymeric hydrogels, such gel exhibit a transition between sol and gel states. Here, we report on a spatial heterogeneity during the sol-to-gel transition by a particle tracking technique. The sol obtained by disrupting the gel was heterogeneous in terms of its physical properties. The extent of heterogeneity in the sol decreased as the re-gelation proceeded.

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Disciplines

Chemistry | Physical Sciences and Mathematics

Keywords

Supramolecular chemistry; Nanogels; Mesoscopic phenomena (Physics)

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