A new rearranged dolabellane diterpene from the soft coral Clavularia inflata

College

College of Science

Department/Unit

Chemistry

Document Type

Article

Source Title

Natural Product Research

Volume

22

Issue

9

First Page

814

Last Page

819

Publication Date

6-15-2008

Abstract

A new dolabellane type diterpene 1 has been isolated through its acetate 1a. The structure of 1a was elucidated by extensive 1D and 2D NMR spectroscopy and confirmed by mass spectrometry. The structure of 1 was deduced by comparison of its NMR spectral data with those of 1a, while its relative stereochemistry was deduced by NOESY. The absolute stereochemistry of C-7 was determined by analyses of 1 separately esterified with R and S O-mandelic acids.

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Digitial Object Identifier (DOI)

10.1080/14786410701640528

Disciplines

Chemistry

Keywords

Diterpenes; Alcyonacea—Analysis

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