Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage
College
College of Science
Department/Unit
Chemistry
Document Type
Article
Source Title
Dalton Transactions
Publication Date
2021
Abstract
The crystal structure of an unprecedented silver complex of O-acetylsinigrin has shown chelating bonds of the sulfated thiohydroximate and an η2-bond of the ethylene moiety with Ag(i). Mechanistic studies on the formation and decomposition of the complex by the 1H NMR measurements and theoretical calculations with the DFT method indicated relevance to the glucosinolate degradation in biological systems.
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Digitial Object Identifier (DOI)
10.1039/d1dt00695a
Recommended Citation
Alba, L. D., Hatanaka, T., Franco, F. C., Nojiri, M., Noel, M. G., & Funahashi, Y. (2021). Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage. Dalton Transactions https://doi.org/10.1039/d1dt00695a
Disciplines
Chemistry
Keywords
Glucosinolates; Silver ions; Scission (Chemistry)
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