Spectrophotometric study of some nickel (II) complexes with N, N'-Dibenzylthiourea as ligand

Date of Publication

1984

Document Type

Bachelor's Thesis

Degree Name

Bachelor of Science in Chemistry

Subject Categories

Chemistry

College

College of Science

Department/Unit

Chemistry

Thesis Adviser

Dr. Luzvisminda U. Rivero

Abstract/Summary

Nickel (II) complexes are prepared by reacting two types of nickel salt with N,N'-dibenzylthiourea. Spectrophotometric analysis revealed that the addition of the ligand affected the absorption band at the max for both types of nickel salt. Spectrophotometric monitoring of the aging of the nickel nitrate solutions confirmed that the same species of the complex is involved in the solution. Aging slows down the completion of the reaction on titration with 10-3M sodium thiosulfate solution. But 4.42 ml is needed to reach the equivalence point of a 50 ml of 10-3M solution of nickel nitrate plus ligand. The potential at the equivalence point is 39.5 mV.

Abstract Format

html

Language

English

Format

Print

Accession Number

TU03290

Shelf Location

Archives, The Learning Commons, 12F, Henry Sy Sr. Hall

Physical Description

[8], 60 leaves; illustrations; 28 cm.

Keywords

Spectrophotometry; Nickel

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