Binder-free centimeter-long V2O5 nanofibers on carbon cloth as cathode material for zinc-ion batteries

Document Type

Article

Source Title

Energies

Volume

13

Issue

31

Publication Date

2020

Abstract

Recently, rechargeable aqueous zinc-ion batteries (AZBs) have attracted extensive interest due to their safety, abundance, low cost, and low toxicity. However, aqueous electrolytes require a polymeric binder to prevent the dissolution of the active material in addition to its binding properties. This study highlights binder-free, centimeter-long, single-crystal, V2O5 nanofibers (BCS-VONF) on carbon cloth, as the cathode material for AZBs synthesized via a simple one-step hydrothermal process. BCS-VONF in 3.0 M Zn(OTf)2 exhibit promising electrochemical performance with excellent capacity retention. Even in the absence of a binder, BCS-VONF were found to be very stable in 3.0 M Zn(OTf)2. They will not yield to the dissolution and detachment of the active material on the current collector. The novel strategy described in this study is an essential step for the development of BCS-VONF on carbon cloth, as a promising cathode material for AZBs.

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Keywords

Zinc ion batteries; Nanofibers; Binders (Materials); Cathodes

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