Title

Novel tetrathiafulvalene derivatives and macrocycles with sugar units: Synthesis and characterization

Date of Publication

1998

Document Type

Dissertation

Degree Name

Doctor of Philosophy in Chemistry

Subject Categories

Chemistry

College

College of Science

Department/Unit

Chemistry

Thesis Adviser

Gerardo C. Janairo

Defense Panel Chair

Eric Camilo R. Punzalan

Defense Panel Member

Jaime Raul O. Janairo
Wyona C. Patalinghug
Anamy Ma. C. Paano
Nancy Lazaro Llanos

Abstract/Summary

Novel tetrathiafulvalene (TTF) derivatives an macrocycles containing glucose units were synthesized. TTF is an electron rich molecule capable of pi-pi interaction while glucose is polyhydroxylated and has the ability to form hydrogen bonds. The macrocycle synthesis involves the stepwise deprotection of cyanoethyl protected TTF, reaction with acetylated dihaloglucose, followed by hydrolysis.

Abstract Format

html

Language

English

Format

Print

Accession Number

TG02780

Shelf Location

Archives, The Learning Commons, 12F Henry Sy Sr. Hall

Physical Description

145 numb. leaves

Keywords

Chemical reactions; Derivatization; Sugar--Inversion; Hydrolysis; Biosynthesis

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